The FWHM value is determined by finding the two points farthest from each other within the integration boundaries where the background-subtracted intensity on the chromatogram is at least half of the background-subtracted height at the apex of the peak. Here is a page which shows how Skyline calculates the background level of an integrated peak: https://skyline.ms/wiki/home/software/Skyline/page.view?name=tip_peak_calc
If you have questions about "FWB" (full width at base), you might be asking how Skyline decides where to place the peak boundaries themselves. I do not know of anything which talks about exactly how Skyline decides where exactly to put those peak boundaries.