There are a couple of different ways that you could get this data to work with Skyline.
One way is to use the "Spectrum Filter" feature to tell Skyline that a particular Precursor in the Targets tree should only use spectra with a specific collision energy.
You can read about that feature here:
https://skyline.ms/home/software/Skyline/wiki-page.view?name=SpectrumFilters
A better way would be to set things up so that the collision energies that you acquired are the same energies that Skyline would have used when exporting a collision energy optimization PRM method. That would involve using the Document Grid to set the "Precursor Explicit Collision Energy" value to 25 and using the "Collision Energy" dropdown on the "Prediction" tab at "Settings > Transition Settings" to set the "Step size" to 10.
It might be tricky to get either of these ways to work, so the easiest thing might be for you to send us your data files and we'll get things set up for you.
In Skyline you can use the menu item:
File > Share
to create a .zip file containing your Skyline document and supporting files including extracted chromatograms.
The Share Document dialog gives you the option of including the .raw files in the .zip file. Alternatively, you could send us the .raw files separately.
Files which are less than 50MB can be attached to these support requests. Larger files can always be uploaded here:
https://skyline.ms/files.url
-- Nick