The reason that you are seeing #N/A probably has something to do with the Normalization Method that you have selected in:
Settings > Peptide Settings > Quantification
If you would like, you can send us your Skyline document.
In Skyline, you can use the menu item:
File > Share > (complete)
to create a .zip file containing your Skyline document and supporting files, including extracted chromatograms.
If that .zip file is less than 50MB then you can attach it to this support request.
Otherwise, you can upload it here:
https://skyline.ms/files.url